Benzilic acid rearrangement

Rearrangement of benzil to benzilic acid via aryl migration.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Subscribe and save

Springer+ Basic €32.70 /Month

Buy Now

Price includes VAT (France)

eBook EUR 71.68 Price includes VAT (France)

Softcover Book EUR 89.66 Price includes VAT (France)

Tax calculation will be finalised at checkout

Purchases are for personal use only

Similar content being viewed by others

[9, 9]-Sigmatropic shifts in acid-catalyzed benzidine-type rearrangements

Article 10 September 2018

Recent advances in the synthesis of benzimidazoles (microreview)

Article 01 October 2016

Acid catalyzed rearrangements of aryl 3-(2-nitroaryl)oxiran-2-yl ketones

Article 01 March 2020

References

  1. Liebig, J. Justus Liebigs Ann. Chem.1838, 27. Justus von Liebig (1803−1873) pursued his Ph.D. in organic chemistry in Paris under the tutelage of Joseph Louis Gay- Lussac (1778−1850). He was appointed the Chair of Chemistry at Giessen University, which incited a furious jealousy amongst several of the professors already working there because he was so young. Fortunately, time would prove the choice was a wise one for the department. Liebig would soon transform Giessen from a sleepy university to a mecca of organic chemistry in Europe. Liebig is now considered the father of organic chemistry. Many classic name reactions were published in the journal that still bears his name, Justus Liebigs Annalen der Chemie. 2 Google Scholar
  2. Zinin, N. Justus Liebigs Ann. Chem.1839, 31, 329. Google Scholar
  3. Georgian, V.; Kundu, N. Tetrahedron1963, 19, 1037–1049. ArticleCASGoogle Scholar
  4. Robinson, J. M.; Flynn, E. T.; McMahan, T. L.; Simpson, S. L.; Trisler, J. C.; Conn, K. B. J. Org. Chem.1991, 56, 6709–6712. ArticleCASGoogle Scholar
  5. Fohlisch, B.; Radl, A.; Schwetzler-Raschke, R.; Henkel, S. Eur. J. Org. Chem.2001, 4357–4365. Google Scholar
  6. Patra, A.; Ghorai, S. K.; De, S. R.; Mal, D. Synthesis2006, 15, 2556–2562. Google Scholar
  7. Selig, P.; Bach, T. Angew. Chem. Int. Ed.2008, 47, 5082–5084. ArticleCASGoogle Scholar
  8. Kumar, R. R.; Balasubramanian, M. Benzilic Acid Rearrangement. In Name Reactions for Homologations-Part II; Li, J. J., Ed.; Wiley: Hoboken, NJ, 2009, pp 395–405. (Review). Google Scholar
  9. Sultana, N.; Fabian, W. M. F. Beilstein J. Org. Chem.2013, 9, 594–601. ArticleCASGoogle Scholar

Author information

Authors and Affiliations

  1. Department of Chemistry College of Arts and Sciences, University of San Francisco, San Francisco, CA, USA Jie Jack Li
  1. Jie Jack Li